Search results for " irradiation effects"

showing 7 items of 7 documents

In-situ observation of beta-ray induced UV optical absorption in a-SiO2: radiation darkening and room temperature recovery

2006

International audience; We studied the optical absorption in the 3.0-6.2 eV range induced in bulk amorphous SiO2 by beta-ray irradiation up to similar to 1 MGy at room temperature. The induced absorption was measured in situ both during irradiation and in the post irradiation time. Our data evidence E', center as the main defect induced by irradiation and the partial decay of their absorption band at about 5.8 eV after irradiation. A quantitative analysis of the time evolution of the induced absorption shows that the transmission recovery observed after irradiation is compatible with the reaction of radiation-induced defects with H-related (H-2, H2O) species diffusing in the amorphous matrix

Absorption spectroscopySilica irradiation effects absorptionAnalytical chemistryOptical spectroscopyWater in glass02 engineering and technology01 natural scienceslaw.inventionAbsorptionlawElectron spin resonance0103 physical sciencesBeta particleMaterials ChemistryOptical fibersIrradiationElectron paramagnetic resonanceAbsorption (electromagnetic radiation)Spectroscopy010302 applied physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]RadiationPhotoinduced effectsChemistryirradiation effectsSettore FIS/01 - Fisica SperimentaleSilica021001 nanoscience & nanotechnologyCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsAmorphous solidAbsorption bandCeramics and Composites[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Defects0210 nano-technology
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The role of impurities in the irradiation induced densification of amorphous SiO(2).

2011

In a recent work (Buscarino et al 2009 Phys. Rev. B 80 094202), by studying the properties of the (29)Si hyperfine structure of the E'(γ) point defect, we have proposed a model able to describe quantitatively the densification process taking place upon electron irradiation in amorphous SiO(2) (a-SiO(2)). In particular, we have shown that it proceeds heterogeneously, through the nucleation of confined densified regions statistically dispersed into the whole volume of the material. In the present experimental investigation, by using a similar approach on a wider set of materials, we explore how this process is influenced by impurities, such as OH and Cl, typically involved in relevant concent…

Materials scienceNucleationCondensed Matter PhysicsCrystallographic defectAmorphous solidlaw.inventionChemical engineeringImpuritylawamorphous silicon dioxide sio2 irradiation effects electron irradiation point defects electron paramagnetic resonance densityElectron beam processingGeneral Materials ScienceIrradiationElectron paramagnetic resonanceHyperfine structureJournal of physics. Condensed matter : an Institute of Physics journal
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Irradiation induced defects in fluorine doped silica

2008

International audience; The role of fluorine doping in the response to UV pulsed laser and c radiation of silica preforms and fibers was studied using electron spin resonance (ESR) spectroscopy. Exposure to radiation mainly generates E0 centers, with the same effectiveness in fibers and in preforms. The E'concentration in F-doped silica fibers is found to increase with UV energy fluence till a saturation value, consistently with a precursor conversion process. These results show the fluorine role in reducing the strained Si–O bonds thus improving the radiation hardness of silica, also after drawing process.

Nuclear and High Energy Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Optical fiberMaterials scienceOptical fiberDopingchemistry.chemical_elementSilicaPhotochemistryCrystallographic defectSilica irradiation effects fluorine dopinglaw.inventionNuclear magnetic resonancechemistrylawElectron spin resonanceHalogenPACS: 71.55.Jv; 61.72.Ww; 76.30.Mi; 61.80.Ed; 61.80.BaFluorineDefectsIrradiationElectron paramagnetic resonanceSpectroscopyInstrumentationFluorine doping
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Defect-related visible luminescence of silica nanoparticles

2013

The high photon emissivity in the visible spectral range is one of the most relevant phenomena emerging from the reduction of silica down to nanoscale; hence it is promising for the development of optical nanotechnologies (down converter, probes, display). It is well accepted that the origin of this luminescence is related to the high specific surface (~100 m2/g) that favors the formation of optically active defects at the nanosilica surface. With the aim to clarify the role of specific luminescent defects, here we report a detailed study of spectral and decay features by time-resolved photoluminescence spectra under a visible-UV tunable laser excitation. Our study is carried out on differe…

Silica nanoparticlesControlled atmosphereMaterials scienceAnalytical chemistryUv lasersilica nanoparticles time resolved luminesce surface defectssilica nanoparticles time-resolved luminescence surface defects laser irradiation effectsLuminescence spectraIrradiationCondensed Matter PhysicsPhotochemistryLuminescenceBlue band
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Luminescence activity of irradiated SiO2-clathrate Melanophlogite

2013

Silica melanophlogite luminescence irradiation effects
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EPR investigation on the polyamorphic transformation induced by electron irradiation in SiO2 glass

2013

electron paramagnetic resonance EPR E' center amorphous silicon dioxide sio2 irradiation effects densification
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Thermal bleaching of gamma-induced-defects in optical fibers

2012

International audience; Ge-doped and F-doped gamma-irradiated fibers with a maximum accumulated dose of 10 MGy were subjected to isochronal annealing treatments up to 750°C. The thermal treatment influence on the point defect generation and transformation were investigated through Radiation Induced Attenuation (RIA) changes in the visible and IR spectral domains. The thermal bleaching of gammainduced-defects depends on both temperature and composition of optical fibers.

radiationsilica fiber irradiation effects point defects thermal treatment optical measurement[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]silicasense organsoptical measurementthermal treatmentfiber
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